UPMSP Intermediate Chemistry Practice Questions - Uttar Pradesh UPMSP Intermediate (Class 12) Chemistry - Code 152 Exam

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A mixture of nitric acid (68%) and water (32%) forms a maximum boiling azeotrope at 393.5 K. What type of deviation from Raoult's law does this solution exhibit?

Negative deviation from Raoult's law because A-B interactions are stronger than A-A and B-B interactions Positive deviation from Raoult's law because A-B interactions are weaker than A-A and B-B interactions Zero deviation because it behaves as an ideal solution at the azeotropic composition Positive deviation because the total vapor pressure of the solution is maximum

Correct Answer:

Negative deviation from Raoult's law because A-B interactions are stronger than A-A and B-B interactions

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