PRC Chemist Practice Questions - PRC Chemist Licensure Examination Exam

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For an octahedral coordination complex of a d5 transition metal ion like Fe(III), which set of conditions favors a low-spin configuration?

A strong-field ligand like CN⁻ and large crystal field splitting energy (Δo > P) A weak-field ligand like F⁻ and small crystal field splitting energy (Δo < P) A strong-field ligand like CN⁻ and small pairing energy (Δo < P) A weak-field ligand like Cl⁻ and large pairing energy (Δo > P)

Correct Answer:

A strong-field ligand like CN⁻ and large crystal field splitting energy (Δo > P)

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