Meister Lackierer Practice Questions - Meisterprüfung Lackierer (Austria) Exam

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What is the chemical consequence when a 2K polyurethane isocyanate hardener (containing free -NCO groups) is exposed to atmospheric moisture or water in the compressed air supply?
Correct Answer:
The isocyanate reacts with water to form an unstable carbamic acid, which rapidly decarboxylates into an amine and carbon dioxide (CO2) gas, leading to polyurea formation and micro-foaming or pinholes

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